Hydroxylation of phenol with hydrogen peroxide in protic and aprotic solvents on TS-1 catalyst

Autor:	V. V. Potekhin, V. M. Potekhin, E. G. Kohina, V. V. Vasil’ev, V. A. Kulikova
Rok vydání:	2011
Předmět:	Hydroxylation chemistry.chemical_compound Aqueous solution Kinetic model chemistry Hydroquinone General Chemical Engineering Organic chemistry Phenol General Chemistry Hydrogen peroxide Heterogeneous catalysis Catalysis
Zdroj:	Russian Journal of Applied Chemistry. 84:640-648
ISSN:	1608-3296 1070-4272
DOI:	10.1134/s1070427211040148
Popis:	Hydroxylation of phenol with a 25% aqueous solution of hydrogen peroxide in polar protic and aprotic solvents on TS-1 heterogeneous catalyst under various conditions was studied. The major reaction products (hydroquinone, pyrocatechol) and their ratio were determined. A kinetic model describing the hydroxylation in accordance with the Rideal-Eley mechanism was chosen.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1283656fcd202811560a828b2b26738a https://doi.org/10.1134/s1070427211040148 Zobrazit plný text záznamu Full text from SpringerLink