Stereoselective Synthesis of a Potential Sex Pheromone of Stenoma Cecropia (Lepidoptera)

Autor:	F. Ramiandrasoa, Frédérique Tellier
Rok vydání:	1990
Předmět:	chemistry.chemical_classification Stereochemistry Organic Chemistry chemistry.chemical_element Alcohol Zinc Aldehyde Coupling reaction Catalysis chemistry.chemical_compound chemistry Reagent Organic chemistry Stereoselectivity Palladium
Zdroj:	Synthetic Communications. 20:333-344
ISSN:	1532-2432 0039-7911
DOI:	10.1080/00397919008052773
Popis:	A convenient preparation of (Z, E) 9, 11-and (Z, Z) 9, 11-tetradecadien-1-yl and (9Z) 9, 11-tetradecenyn-1-yl acetate, alcohol and aldehyde with 99.5 % stereoisomeric purity is described. The key step of this synthesis is the carbocupration of acetylene followed by palladium catalyzed cross coupling reaction with the appropriate zinc reagent.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::127fce5b7490b7c3ba73201f0964023f https://doi.org/10.1080/00397919008052773 Zobrazit plný text záznamu