Activation of radical addition to graphene by chemical hydrogenation
| Autor: | David A. Kidwell, Jeremy T. Robinson, Keith E. Whitener, Woo-Kyung Lee, Cy R. Tamanaha, Paul E. Sheehan, Rory Stine |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Hydrogen
Graphene General Chemical Engineering Inorganic chemistry chemistry.chemical_element 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences 0104 chemical sciences law.invention symbols.namesake chemistry X-ray photoelectron spectroscopy law Electrical resistivity and conductivity Chemical groups symbols Chlorine Dehydrogenation 0210 nano-technology Raman spectroscopy |
| Zdroj: | RSC Advances. 6:93356-93362 |
| ISSN: | 2046-2069 |
| Popis: | We report several methods of chemical dehydrogenation of hydrogenated graphene (HG), characterizing the results using Raman, X-ray photoelectron spectroscopy, and electrical conductivity measurements. Notably, the hydrogen–graphene bonds appear to activate the graphene toward subsequent reaction such that, in several cases, the addition of the dehydrogenating agent to the graphene accompanies the removal of hydrogen. We compare the uptake of chemical groups on HG to those on pristine graphene and find that HG reacts more readily than pristine graphene with radical generators such as chlorine and AIBN. |
| Databáze: | OpenAIRE |
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