Autor:	Marcus C. Hansen, Xavier Verdaguer, Scott C. Berk, Stephen L. Buchwald
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Polymethylhydrosiloxane chemistry Hydrosilylation Yield (chemistry) Difluoride Organic chemistry General Medicine Catalysis
Zdroj:	ChemInform. 29
ISSN:	1522-2667 0931-7597
Popis:	A convenient method for the conversion of lactones to lactols is described. The hydrosilylation to lactols is carried out via air-stable titanocene difluoride or a titanocene diphenoxide precatalyst using inexpensive polymethylhydrosiloxane (PMHS) as the stoichiometric reductant. These procedures have been demonstrated with a variety of substrates and proceed in good to excellent yield.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::123f840a1799b53e7a0dc7080fa813f6 https://doi.org/10.1002/chin.199828134 Zobrazit plný text záznamu Plný text