Mechanism of Thiono-Thiolo Isomerization of Thiophosphates. Kinetic Evedence for Hilgetag's Hypothesis

Autor:	Jan Adamus, W. Reimschüssel
Rok vydání:	1990
Předmět:	Tetramethylammonium chemistry.chemical_classification Organic Chemistry Salt (chemistry) Photochemistry Kinetic energy Biochemistry Inorganic Chemistry chemistry.chemical_compound chemistry Mechanism (philosophy) Computational chemistry Acetonitrile Isomerization Demethylation
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. :77-80
ISSN:	1563-5325 1042-6507
DOI:	10.1080/10426509008038911
Popis:	Kinetic evidence is given for Hilgetag's mechanistic conception of the thiono-thiolo isomerization of O,O-dimethyl and O-methyl thionophosphates in acetonitrile solutions containing tetramethylammonium salts with anions derived from the corresponding thionophosphates by demethylation. Some kinetic effects of reactant structures, solvents, and trimethylammonium cation of a salt are mentioned.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::123a7fd3521e8e09dbdf1476e1091a3f https://doi.org/10.1080/10426509008038911 Zobrazit plný text záznamu