Consecutive substitution for three nitro groups in 1,3,5-trinitrobenzene under the action of benzotriazole and other nucleophiles

Autor:	Vadim V. Kachala, Mikhail D. Dutov, Svyatoslav A. Shevelev, Oleg Yu. Sapozhnikov
Rok vydání:	2002
Předmět:	chemistry.chemical_compound Meta Benzotriazole Nucleophile Chemistry Nucleophilic aromatic substitution Stereochemistry Substitution (logic) Nucleophilic substitution Nitro 1 3 5-Trinitrobenzene General Chemistry
Zdroj:	Mendeleev Communications. 12:231-232
ISSN:	0959-9436
DOI:	10.1070/mc2002v012n06abeh001688
Popis:	The N-benzotriazole unit and the nitro group are similar in the activating effect of nucleophilic substitution for an aromatic nitro group at the meta position; this fact makes it possible to replace consecutively all of the three nitro groups in 1,3,5-trinitrobenzene.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1239a48ed720d9a1a578b66a27da33e0 https://doi.org/10.1070/mc2002v012n06abeh001688 Zobrazit plný text záznamu Full Text from ScienceDirect