A new and efficient Baeyer–Villiger rearrangement of flavanone derivatives by the methyltrioxorhenium/H2O2 catalytic system

Autor:	Enrico Mincione, Roberta Bernini, Giovanni Aliotta, Raffaele Saladino, Manuela Cortese, Anna Oliva
Rok vydání:	2001
Předmět:	chemistry.chemical_compound chemistry Homogeneous Organic Chemistry Drug Discovery Biochemistry Flavanone Combinatorial chemistry Catalysis
Zdroj:	Tetrahedron Letters. 42:5401-5404
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(01)01005-x
Popis:	The catalytic Baeyer–Villiger rearrangement of flavanones is described by the use of the homogeneous methyltrioxorhenium (MTO)/H2O2 system. In these experimental conditions 3,4-dihydro-4-phenyl-1,5-benzodioxepin-2-ones and previously not reported para-quinone derivatives have been obtained in mild experimental conditions from acceptable to good yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1232c1e699ee57f890c4684ba6bd0890 https://doi.org/10.1016/s0040-4039(01)01005-x Zobrazit plný text záznamu Full Text from ScienceDirect