Effect of non-covalent self-dimerization on the spectroscopic and electrochemical properties of mixed Cu(i) complexes

Autor: Joaquín Cáceres-Vásquez, Danilo H. Jara, Juan Costamagna, Fabián Martínez-Gómez, Carlos P. Silva, Luis Lemus, Eleonora Freire, Ricardo Baggio, Cristian Vera, Juan Guerrero
Rok vydání: 2023
Předmět:
Zdroj: RSC Advances. 13:825-838
ISSN: 2046-2069
DOI: 10.1039/d2ra05341a
Popis: Organized crystal packing from non-covalent dimers and the self-dimerization in solution of Cu(NN′)(PPh3)Br] were characterized. Differences in Cu(ii)/Cu(i) potentials between the monomer and dimer are modulated by the non-covalent interactions.
Databáze: OpenAIRE