Effect of non-covalent self-dimerization on the spectroscopic and electrochemical properties of mixed Cu(i ) complexes
Autor: | Joaquín Cáceres-Vásquez, Danilo H. Jara, Juan Costamagna, Fabián Martínez-Gómez, Carlos P. Silva, Luis Lemus, Eleonora Freire, Ricardo Baggio, Cristian Vera, Juan Guerrero |
---|---|
Rok vydání: | 2023 |
Předmět: | |
Zdroj: | RSC Advances. 13:825-838 |
ISSN: | 2046-2069 |
DOI: | 10.1039/d2ra05341a |
Popis: | Organized crystal packing from non-covalent dimers and the self-dimerization in solution of Cu(NN′)(PPh3)Br] were characterized. Differences in Cu(ii)/Cu(i) potentials between the monomer and dimer are modulated by the non-covalent interactions. |
Databáze: | OpenAIRE |
Externí odkaz: |