Rapid access to t-butylalkylated olefins enabled by Ni-catalyzed intermolecular regio- and trans-selective cross-electrophile t-butylalkylation of alkynes
| Autor: | Yi-Zhou Zhan, Huan Meng, Wei Shu |
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| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | Chemical Science. 13:4930-4935 |
| ISSN: | 2041-6539 2041-6520 |
| DOI: | 10.1039/d2sc00487a |
| Popis: | A direct reductive cross-dialkylation of alkynes is achieved to afford trans-dialkylated olefins using two distinct alkyl bromides. The reaction undergoes with exclusive chemo-, regio- and stereoselectivity without the use of organometallic reagents. |
| Databáze: | OpenAIRE |
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