Synthesis of some new diarylsulphides and diarylsulphones containing a quinazol-4-one moiety

Autor:	M. M. Kandeel, M. A. Abbady, Morsy M. Ali
Rok vydání:	2007
Předmět:	Hydrogen Infrared General Engineering chemistry.chemical_element General Medicine medicine.disease_cause Catalysis chemistry.chemical_compound Acetic acid chemistry medicine Moiety Organic chemistry Piperidine Ultraviolet
Zdroj:	Journal of Chemical Technology and Biotechnology. 31:111-114
ISSN:	0142-0356
DOI:	10.1002/jctb.503310115
Popis:	4-Amino-4′-nitrodiphenylsulphide and 4-amino-2′-nitrodiphenyl sulphide (I) were smoothly condensed with 2-methyl-3,1-benzoxazin-4-one (II) to produce the corresponding 2-methyl-3-diphenylsulphidoquinazol-4-ones (III). 2-Styryl-3-diphenylsulphidoquinazol-4-ones (IV) were prepared by heating III with the appropriate aromatic aldehydes using piperidine as a basic catalyst. Compounds IV oxidised easily in a hydrogen peroxide-glacial acetic acid mixture to produce the corresponding sulphones (V). The constitution of some of the prepared products is discussed in the light of their infrared and ultraviolet spectra. The biological activities of some of these compounds were tested.
Databáze:	OpenAIRE
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