Capillary electrophoretic separation of inorganic and organic arsenic compounds

Autor:	M. G. Schmid, G. Gübitz, Herbert Greschonig
Rok vydání:	1998
Předmět:	Electrophoresis chemistry.chemical_compound Capillary electrophoresis Chromatography chemistry Sodium Arsenate chemistry.chemical_element Electrolyte Phosphate Biochemistry Arsenic Arsenite
Zdroj:	Fresenius' Journal of Analytical Chemistry. 362:218-223
ISSN:	1432-1130 0937-0633
Popis:	Capillary zone electrophoresis was used to separate arsenite, arsenate, dimethylarsinic and diphenylarsinic acid, methanearsonic acid, phenyl- and p-aminophenyl arsonic acid, phenylarsineoxide and phenarsazinic acid. Anionic and uncharged species were separated in a fused silica capillary with on-column UV detection at 200 nm. A 15 mM phosphate solution adjusted to pH 6.5 containing 10 mM sodium dodecylsulfonate served as background electrolyte. The influence of pH and applied voltage on separation efficiency, as well as the feasibility of identification of arsenic compounds in spiked urine, were investigated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::11ed8efecafe826ad8cb566398a8242a https://doi.org/10.1007/s002160051063 Zobrazit plný text záznamu Full text from SpringerLink