Rupture and combustion characteristics of lithium-ion battery under overcharge
Autor: | Fei Gao, Ming-xin Shan, Peng-long Zhao, Cong-jie Wang, Yan-Li Zhu, Qing-fen Meng, Qi-bing Wu |
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Rok vydání: | 2021 |
Předmět: |
Battery (electricity)
Overcharge Materials science Argon Thermal runaway Renewable Energy Sustainability and the Environment 020209 energy Nuclear engineering Energy Engineering and Power Technology chemistry.chemical_element 02 engineering and technology 021001 nanoscience & nanotechnology Combustion Lithium-ion battery law.invention Ignition system chemistry law 0202 electrical engineering electronic engineering information engineering Electrical and Electronic Engineering Current (fluid) 0210 nano-technology |
Zdroj: | Journal of Energy Storage. 38:102571 |
ISSN: | 2352-152X |
DOI: | 10.1016/j.est.2021.102571 |
Popis: | To clarify the evolution of thermal runaway of lithium-ion batteries under overcharge, the prismatic lithium-ion batteries are overcharged at various current rates in air and argon. The whole process with the charge rate higher than 0.1C in air includes three parts, which are expansion, rupture and combustion processes, respectively. The expansion process can be divided into two stages based on the change of surface temperature, and the temperatures at cell burst point are very close at various charge rates. The rupture process begins from the battery burst point. The pressure generated by rupture is less than 61 kPa at different charge rates, while it can reach 389 kPa in the following combustion process at 1C. The combustion process can be divided into four stages based on the obvious change of combustion phenomenon, which are ignition, violent combustion, stable combustion and extinguishing, respectively. Combustible gas was mainly CO, accounting for 32%. Three element factors of combustion under overcharge are clarified: combustible spouted out from the battery, high temperature electrode active substance, and oxygen in the environment, respectively. The results of this work can provide some information for the safety and fire protection of lithium-ion-battery based devices. |
Databáze: | OpenAIRE |
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