Peculiarities of surface morphology and composition of polymer - vanadium oxide composite films
| Autor: | Petro Litvin, Sergey Svechnikov, Petro Smertenko, Iudmila Grebinska, Vitaliy Golovatiy, Oksana Litvin, Nikolay Guba, Igor Prokopenko, V. D. Pokhodenko, Vladimir Shabel'nikov, Larisa Fenenko |
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| Rok vydání: | 2002 |
| Předmět: |
chemistry.chemical_classification
Conductive polymer Materials science Nanocomposite Composite number General Chemistry Polymer Condensed Matter Physics Oligomer Vanadium oxide chemistry.chemical_compound Chemical engineering chemistry Polymer chemistry Mass spectrum Molecule General Materials Science |
| Zdroj: | Molecular Crystals and Liquid Crystals. 384:69-76 |
| ISSN: | 1563-5287 1542-1406 |
| Popis: | The surface morphology of the polymer films based onpolyepoxypropylcarbazole and 3,6-di-Br-polyepoxypropylcarbazole with V 2 O 5 was investigated by Atom Force Microscopy (AFM). The surface of composite has been found to be a chaotically intertwining of V 2 O 5 fibres intermittent with inclusions of a corresponding polymer. Polymer inclusions are single ellipsoidal grains for PEPC composite and an aggregate of small grains for 3,6-di-Br-PEPC sample. Both V 2 O 5 fibres and polymer inclusions have smaller size in 3,6-di-Br-PEPC. The mass spectra of compounds under investigation have been obtained. Both PEPC oligomer ions and those identified as complexes of M PEPC oligomers with V 2 O 4 molecule and 3M PEPC oligomers with V 2 O 5 molecule have been observed in mass spectrum of PEPC+V 2 O 5 composite at the emitter temperature from 120°C up to 430°C. 2M, 3M and even 5M PEPC olygomers were observed in mass spectrum of 3,6-di-Br-PEPC+V 2 O 5 composite at the emitter temperature from 20°C up to 600°C and 2M 3,... |
| Databáze: | OpenAIRE |
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