Recent Progress towards the Transition-Metal-Catalyzed Dearomatizing Spirocyclization Reactions of Indolyl Ynones

Autor: Wen-Bo Shen, Kua-Fei Wei, Xiao-Lei Jiang, Guang-Xin Ru, Xiu-Hong Zhu
Rok vydání: 2022
Předmět:
Zdroj: Synlett. 34:211-220
ISSN: 1437-2096
0936-5214
DOI: 10.1055/a-1970-4290
Popis: Dearomatizing spirocyclization reactions are very appealing synthetic strategies to generate functionalized three-dimensional scaffolds from simple two-dimensional precursors. Recently, the field of transition-metal-catalyzed dearomatizing spirocyclization reactions of indolyl ynones has burgeoned, as the construction of synthetically challenging quaternary spirocyclic carbons is easily achieved. In this review, we introduce an overview of advances in the transition-metal-catalyzed dearomatizing spirocyclization reactions of indolyl ynones, with the reactions being categorized according to type of catalyst.
Databáze: OpenAIRE