The Vinylidene/Acyl Coupling at Rhenium Centers
| Autor: | H. William Bosch, Wolfgang Beck, Sibylle Feracin, Hans-Ulrich Hund, Heinz Berke, Elisabeth Lippmann |
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| Rok vydání: | 1992 |
| Předmět: |
Structure analysis
Stereochemistry Organic Chemistry chemistry.chemical_element Crystal structure Rhenium Coupling (probability) Biochemistry Catalysis Inorganic Chemistry chemistry.chemical_compound Chemical coupling chemistry Phenylacetylene Drug Discovery X-ray crystallography Molecule Physical and Theoretical Chemistry |
| Zdroj: | Helvetica Chimica Acta. 75:1305-1312 |
| ISSN: | 1522-2675 0018-019X |
| DOI: | 10.1002/hlca.19920750432 |
| Popis: | The reaction of [Re(CO3)L2Cl] (L = (MeI)3P, 1a; L = (i-PrO)3P, 1b; L = (PhO)3P, 1c; L = Me3P, 1d; L = Et3P, 1e) with t-BuLi and phenylacetylene in THF affords bis (phosphorus donor) (dicarbonyl) {η2(C,O)-[(E)-4,4-dimethyl-3-oxo-1-phenylpent-1-3n-2-yl]}rhenium (L = (MeO)3P, 2b; L = (PhO)3P, 2c; L = Me3P, 2d; L = Et3P, 2c). Compounds 2b and 2d were characterized by X-ray structure analysis. |
| Databáze: | OpenAIRE |
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