Catalytic activity of a microporous–mesoporous composite towards liquid phase oxidation of diphenylmethane

Autor:	Priyanka Kalita, Doli Rani Das, Anup Kumar Talukdar, Debojit Hazarika
Rok vydání:	2021
Předmět:	chemistry.chemical_element Diphenylmethane General Chemistry Microporous material Catalysis chemistry.chemical_compound chemistry Chemical engineering Materials Chemistry Benzophenone Hydrothermal synthesis Zeolite Mesoporous material Cobalt
Zdroj:	New Journal of Chemistry. 45:18947-18956
ISSN:	1369-9261 1144-0546
DOI:	10.1039/d1nj03577k
Popis:	Hydrothermal synthesis of a ZSM-5/MCM-41 composite has been carried out from pre-synthesized ZSM-5 zeolite as a silica source and CTAB as a template. The ZSM-5/MCM-41 composite materials were further loaded with varying wt% of cobalt with respect to ZSM-5 by an in situ modification method using cobaltous nitrate as a metal source. Detailed analysis of the synthesized materials was performed using different characterization techniques such as PXRD, FT-IR, TGA, UV-Vis DRS, N2 adsorption–desorption and SEM-EDX. The catalytic activity of the synthesized materials for liquid phase oxidation of diphenylmethane was investigated in the presence of 70% TBHP as an oxidant where benzophenone was obtained as a major product. The effects of various reaction parameters were studied to perceive the conversion of diphenylmethane and enhance the selectivity towards benzophenone.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::11b0a8e09f661e6edbe90abe762a134a https://doi.org/10.1039/d1nj03577k Zobrazit plný text záznamu