Optical characterization of CuIn1−xGaxSe2 alloy thin films by spectroscopic ellipsometry

Autor:	Robert W. Birkmire, P.D. Paulson, William N. Shafarman
Rok vydání:	2003
Předmět:	Soda-lime glass Materials science chemistry Ellipsometry Analytical chemistry General Physics and Astronomy chemistry.chemical_element Thin film Gallium Molar absorptivity Ternary operation Refractive index Indium
Zdroj:	Journal of Applied Physics. 94:879-888
ISSN:	1089-7550 0021-8979
DOI:	10.1063/1.1581345
Popis:	Optical constants of polycrystalline thin film CuIn1−xGaxSe2 alloys with Ga/(Ga+In) ratios from 0 to 1 have been determined by spectroscopic ellipsometry over an energy range of 0.75–4.6 eV. CuIn1−xGaxSe2 films were deposited by simultaneous thermal evaporation of elemental copper, indium, gallium and selenium. X-ray diffraction measurements show that the CuIn1−xGaxSe2 films are single phase. Due to their high surface roughness, the films are generally not suitable for ellipsometer measurements. A method is presented in which spectroscopic ellipsometer measurements were carried out on the reverse side of the CuIn1−xGaxSe2 films immediately after peeling them from Mo-coated soda lime glass substrates. A detailed description of multilayer optical modeling of ellipsometric data, generic to ternary chalcopyrite films, is presented. Accurate values of the refractive index and extinction coefficient were obtained and the effects of varying Ga concentrations on the electronic transitions are presented.
Databáze:	OpenAIRE
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