Synthesis of perfluoropolyethers via hydrocarbon polyesters: a new general method

Autor:	G. E. Gerhardt, D. F. Persico, Richard J. Lagow
Rok vydání:	1985
Předmět:	Polyester chemistry.chemical_classification Colloid and Surface Chemistry General method Hydrocarbon chemistry Polymer chemistry Chemical modification General Chemistry Biochemistry Catalysis
Zdroj:	Journal of the American Chemical Society. 107:1197-1201
ISSN:	1520-5126 0002-7863
Popis:	Synthese en 3 etapes: 1) perfluoration de l'hydrocarbure polyester: 2) reaction de SF 4 avec le carbonyle ester pour produire une unite CF 2 et 3) rupture a haute temperature en perfluoropolyethers et oligomeres volatils. Cas de la conversion des polyesters poly(dimethyl-2,2 propylenesuccinate-1,3) et poly(butyleneadipate-1,4) en structures perfluoropolyether ramifiees et lineaires, respectivement
Databáze:	OpenAIRE
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