Inorganic–Organic Hybrid Molecular Clusters with Cu2I2 Rhomboid Dimer Core as Light-Emitting Coating Materials
| Autor: | Le Lv, Chanchan Xu, Wei Liu, Zhijuan Zhang |
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| Rok vydání: | 2020 |
| Předmět: |
Steric effects
chemistry.chemical_classification Materials science Band gap Dimer Iodide chemistry.chemical_element Nanochemistry 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Biochemistry Copper 0104 chemical sciences Catalysis chemistry.chemical_compound Crystallography chemistry General Materials Science 0210 nano-technology Luminescence |
| Zdroj: | Journal of Cluster Science. 32:1205-1211 |
| ISSN: | 1572-8862 1040-7278 |
| DOI: | 10.1007/s10876-020-01886-5 |
| Popis: | In this paper, a series of light-emitting copper(I) iodide inorganic–organic hybrid clusters has been synthesized, and they are 0D-Cu2I2(fmp)4 (1, fmp = 3-fluoro-5-methyl-pyridine), 0D-Cu2I2(iq)4 (2, iq = isoquinoline), 0D-Cu2I2(ni)4 (3, ni = nicotinonitrile). They are all molecular clusters with Cu2I2 rhomboid dimer core which is the result of steric hindrance of organic ligands. The emissions of these compounds range from green to red in the solid state. The band gaps and emission energies of these compounds could be tuned by selecting different organic ligands. These compounds are solution processable and could be coated onto various substrates as luminescent inorganic–organic hybrid coating materials. |
| Databáze: | OpenAIRE |
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