Determination of Oxides in Fluoride Salts by High-Temperature Fluorination with Potassium Bromotetrafluoride

Autor:	Gerald. Goldberg, A. S. Meyer, J. C. White
Rok vydání:	1960
Předmět:	Bromine trifluoride Magnesium Potassium Inorganic chemistry chemistry.chemical_element Yttrium Oxygen Potassium fluoride Analytical Chemistry chemistry.chemical_compound chemistry Lithium Fluoride Nuclear chemistry
Zdroj:	Analytical Chemistry. 32:314-317
ISSN:	1520-6882 0003-2700
Popis:	A method is described for the determination of oxygen in fluoride salts of yttrium, beryllium, zirconium, and magnesium and in mixtures of these salts with the fluoride salts of sodium and lithium. The fluorinating agent, potassium bromotetrafluoride, which is prepared in a nickel reactor by the addition of bromine trifluoride to potassium fluoride, is reacted with the oxides for 2 hours at 450 deg C to produce oxygen which is then measured tensimetrically. Recovery of oxygen from the pure metal oxides as standards is better than 98% with a coefficient of variation of less than 5%. The precision of analysis of the fluoride salts is better than 10%. The range of oxygen that can be measured is from 0.02 to 10 mg. (auth)
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1161b2344a36d7b16d7f174eab8d2a54 https://doi.org/10.1021/ac60159a004 Zobrazit plný text záznamu