C-Glycosides V: Données mécanistiques sur l'halogénation d'hydrazones et d'oximes dérivées de sucres. Communication préliminaire

Autor:	N. Le-Hong, Br. Baehler, P. F. Livio, J. M. J. Tronchet
Rok vydání:	1971
Předmět:	Inorganic Chemistry endocrine system diseases Stereochemistry Chemistry Organic Chemistry Drug Discovery Halogenation Physical and Theoretical Chemistry Biochemistry Catalysis
Zdroj:	Helvetica Chimica Acta. 54:921-926
ISSN:	0018-019X
DOI:	10.1002/hlca.19710540318
Popis:	The bromination of aldehydo-sugars p-nitrophenylhydrazones has been studied and the gem-bromo-azo intermediates isolated and characterized in some cases. In the same way, in the chlorination of aldehydo-sugars oximes gem-chloro-nitroso intermediates have been obtained and in some instances isolated. These observations support a SE2′ mechanism for such reactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1131ee969bb84da82106195d18fab2c0 https://doi.org/10.1002/hlca.19710540318 Zobrazit plný text záznamu Plný text