Hydrogen-bonding interactions of photoacids: correlation of optical solvatochromism with IR absorption spectra

Autor:	N. Strashnikova, Ben-Zion Magnes, Ehud Pines, Dina Pines
Rok vydání:	2004
Předmět:	Ir absorption Absorption spectroscopy Infrared Chemistry Hydrogen bond Solvatochromism General Chemistry Condensed Matter Physics Photochemistry Spectral line symbols.namesake chemistry.chemical_compound Stokes shift symbols Photoacid General Materials Science
Zdroj:	Solid State Ionics. 168:225-233
ISSN:	0167-2738
Popis:	The effect of specific hydrogen-bonding interactions on the electronic spectra and the infrared (IR) absorption spectra of several naphthol-type photoacids was investigated. A correlation between the p K a * of the photoacid and its optical solvatochromism was observed for R*OH⋯B-type hydrogen bonds using the Kamlet–Taft (K–T) analysis. In addition, a correlation between the spectral shift in the IR stretching frequency of the ROH⋯B bond and the optical Stokes shift in the fluorescence spectra of the photoacids was found.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1125c8026c3eaa080f1d0baa8c6263d7 https://doi.org/10.1016/j.ssi.2003.02.001 Zobrazit plný text záznamu Full Text from ScienceDirect