Observation of random-field behavior in (CO)1−x(N2)xmixtures physisorbed on graphite

Autor: Stefan-Alexander Arlt, H. Wiechert
Rok vydání: 1993
Předmět:
Zdroj: Physical Review Letters. 71:2090-2093
ISSN: 0031-9007
DOI: 10.1103/physrevlett.71.2090
Popis: Heat-capacity studies have been carried out on submonolayers of (CO${)}_{1\mathrm{\ensuremath{-}}\mathit{x}}$(${\mathrm{N}}_{2}$${)}_{\mathit{x}}$ mixtures physisorbed on graphite. We find that pure CO undergoes an end-to-end ordering transition at ${\mathit{T}}_{\mathit{c}}$=5.18 K, which is shown to belong to the two-dimensional Ising universality class. In diluting CO with ${\mathrm{N}}_{2}$ the heat-capacity peaks become progressively rounded until the phase transition is completely suppressed at a ${\mathrm{N}}_{2}$ concentration of only x=0.07. The analysis of the data shows that this behavior is in quantitative agreement with predictions of the random-field theory applied to adsorbed films.
Databáze: OpenAIRE