Highly Efficient Asymmetric Epoxidation of Electron-Deficient α,β-Enones and Related Applications to Organic Synthesis

Autor:	Hai-Feng Wang, Haifeng Cui, Ying-Quan Yang, Yawen Li, Gang Zhao, Junkang Zhang, Changwu Zheng
Rok vydání:	2009
Předmět:	chemistry.chemical_compound Chemistry Enantioselective synthesis Organic synthesis Stereoselectivity General Chemistry Electron Combinatorial chemistry Balasubramide Catalysis
Zdroj:	Advanced Synthesis & Catalysis. 351:1685-1691
ISSN:	1615-4169 1615-4150
DOI:	10.1002/adsc.200900041
Popis:	The asymmetric epoxidation of electron-deficient olefins has been achieved using inexpensive and readily available prolinols as catalysts with good to excellent yields and enantioselectivities. The utility of the resulting chiral epoxides was illustrated by elaboration to several synthetically useful compounds featuring a concise synthesis of (−)-(5R,6S)-balasubramide.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::10c0a97d5d1cb911025f868cb41352e9 https://doi.org/10.1002/adsc.200900041 Zobrazit plný text záznamu Plný text