Stereoconvergent approach to each of the stereoisomeric hydroxydiquinanes based on the anionic [1,3] rearrangement of bicyclo[3.2.1]oct-6-en-2-ols

Autor:	Masako Ueno, Tadao Uyehara, Toshio Sato, Hiroki Hashimoto, Katsura Seki
Rok vydání:	1999
Předmět:	chemistry.chemical_compound Bicyclic molecule Chemistry Organic Chemistry Drug Discovery Organic chemistry Diglyme Solvent effects Biochemistry Toluene Carbanion
Zdroj:	Tetrahedron Letters. 40:511-514
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(98)02389-2
Popis:	The anionic [1,3] rearrangement of both stereoisomeric bicyclo[3.2.1]oct-6-en-2-ols by treatment with KN(TMS) 2 in toluene or in diglyme took place as a stereoconvergent route giving each of the stereoisomeric hydroxydiquinanes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::10b1f870a63838e2effffbd738a87d5a https://doi.org/10.1016/s0040-4039(98)02389-2 Zobrazit plný text záznamu Full Text from ScienceDirect