Some reactions of 3,7-dimethyl-2,3-epoxyoctanal and its derivatives

Autor:	L. A. Yanovskaya, V. N. Samsonova, L. P. Glushko, L. V. Dmitrikova
Rok vydání:	1986
Předmět:	chemistry.chemical_classification Double bond Organic Chemistry Acetal Oxide Epoxide Ring (chemistry) Citral Medicinal chemistry chemistry.chemical_compound Dichlorocarbene chemistry Organic chemistry Knoevenagel condensation
Zdroj:	Chemistry of Heterocyclic Compounds. 22:370-372
ISSN:	1573-8353 0009-3122
DOI:	10.1007/bf00542771
Popis:	The oxide of citral (3,7-dimethyl-2,3-epoxioctanal) readily enters into the Knoevenagel condensation with the formation of the corresponding epoxydienecarboxylic acid. The epoxidation and addition of dichlorocarbene to similar epoxydienes proceeds at the double bond which does not adjoin the epoxide ring. The condensation of the acetal of citral oxide with ketones with the formation of 1,3-dioxolanes proceeds with the participation of the epoxide ring.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::10acfdb536bf7cbae10d444949c5acc2 https://doi.org/10.1007/bf00542771 Zobrazit plný text záznamu Full text from SpringerLink