Production of NiO/N-doped carbon hybrid and its electrocatalytic performance for oxygen evolution reactions

Autor: Dawoon Jang, Haeju Kim, Sungjin Park, Sujin Seok
Rok vydání: 2020
Předmět:
Zdroj: Carbon Letters. 30:485-491
ISSN: 2233-4998
1976-4251
Popis: Oxygen evolution reaction (OER) is an essential step at an anode in electrochemical water-splitting process and requires efficient electrocatalysts to reduce overpotentials. Although precious metal-based materials, such as RuO2, IrO2 and their hybrids with other components, performed excellently as OER electrocatalysts, their high cost has limited practical applications. Consequently, earth-abundant metal components including Fe, Co, and Ni have been investigated as alternatives. In this work, the hybridization of Ni-containing species with conductive carbon-based materials was used to prevent aggregation of active species and improve electrochemical catalytic performance. A new hybrid material composed of NiO nanoparticles and N-doped carbon materials was prepared. The NiO particles with a narrow size distribution were well dispersed on the surface of carbon-based materials. The hybrid showed improved electrocatalytic performance for OER than single components of NiO and N-doped carbon materials.
Databáze: OpenAIRE