The invention of radical reactions. Part XXXIV. Homologation of carboxylic acids to α-keto carboxylic acids by Barton-ester based radical chain chemistry

Autor:	Joseph Cs. Jaszberenyi, Ching-Yuh Chern, Derek H. R. Barton
Rok vydání:	1995
Předmět:	Acrylate chemistry.chemical_compound Chain (algebraic topology) Radical substitution Chemistry Radical Organic Chemistry Drug Discovery Organic chemistry Biochemistry Radical cyclization
Zdroj:	Tetrahedron. 51:1867-1886
ISSN:	0040-4020
DOI:	10.1016/0040-4020(94)01054-4
Popis:	Carboxylic acids can be transformed into the homologous α-keto acids by Barton-ester based radical chemistry. This method was especially successful when ethyl α-trifluoroacetoxy acrylate was used as a radical trap.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::109717633df510386940b2274fe70063 https://doi.org/10.1016/0040-4020(94)01054-4 Zobrazit plný text záznamu Full Text from ScienceDirect