2-(N-Hydroxylamino) sulfone synthesis by indium–iodine-triggered aza-Michael type addition of nitroarenes to vinyl sulfones

Autor: Sun Jung Lee, Jung June Lee, Byeong Hyo Kim, Chong-Hyeak Kim, Young Moo Jun, Byung Min Lee
Rok vydání: 2009
Předmět:
Zdroj: Tetrahedron Letters. 50:484-487
ISSN: 0040-4039
Popis: One-pot reduction-triggered 1,4-addition reaction of various nitroarenes to the α,β-unsaturated sulfones was investigated. In the presence of indium/iodine in MeOH at room temperature, nitroarenes reduced in situ reacted with vinyl sulfones and produced β-(N-hydroxylamino) sulfones in good yields.
Databáze: OpenAIRE