2-(N-Hydroxylamino) sulfone synthesis by indium–iodine-triggered aza-Michael type addition of nitroarenes to vinyl sulfones
Autor: | Sun Jung Lee, Jung June Lee, Byeong Hyo Kim, Chong-Hyeak Kim, Young Moo Jun, Byung Min Lee |
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Rok vydání: | 2009 |
Předmět: | |
Zdroj: | Tetrahedron Letters. 50:484-487 |
ISSN: | 0040-4039 |
Popis: | One-pot reduction-triggered 1,4-addition reaction of various nitroarenes to the α,β-unsaturated sulfones was investigated. In the presence of indium/iodine in MeOH at room temperature, nitroarenes reduced in situ reacted with vinyl sulfones and produced β-(N-hydroxylamino) sulfones in good yields. |
Databáze: | OpenAIRE |
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