N-Iodosuccinimide-mediated intramolecular aglycon delivery

Autor: C. A. Slinn, Antony J. Fairbanks, Richard J. Tennant-Eyles, H. S. Yeates, S. C. Ennis
Rok vydání: 2001
Předmět:
Zdroj: Tetrahedron. 57:4221-4230
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)00308-8
Popis: Enol ethers may be accessed via Tebbe methylenation of either 2- O acetates or para -methoxybenzoates. N -Iodosuccinimide may then be employed to achieve both tethering and thioglycoside activation allowing the stereoselective synthesis of α-glucosides and β-mannosides, either in a one or two step procedure.
Databáze: OpenAIRE