Copolymers containing functional groups intrinsic to the active centers of serine hydrolases: Synthesis and evaluation of catalytic capability
| Autor: | Natalia V. Grinberg, V. P. Chernyshev, A. S. Kovaleva, T. A. Babushkina, E. V. Boltukhina, Tamara P. Klimova, Tatiana V. Burova, V. Ya. Grinberg, Olga E. Zaborina, Vladimir I. Lozinsky, Alexei R. Khokhlov |
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| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
010407 polymers Aqueous solution Polymers and Plastics Chemistry Dimethyl sulfoxide 02 engineering and technology 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Catalysis chemistry.chemical_compound Hydrolysis Materials Chemistry Ceramics and Composites Propionate Copolymer Organic chemistry Imidazole Amine gas treating 0210 nano-technology |
| Zdroj: | Polymer Science Series B. 58:27-37 |
| ISSN: | 1555-6123 1560-0904 |
| DOI: | 10.1134/s156009041601005x |
| Popis: | N-Acryloyl derivatives of histamine, monoethanolamine, and β-alanine, which contain imidazole, hydroxyl, and carboxyl functional groups, respectively, are synthesized and characterized. Copolymers, which are further divided into thermally precipitable and thermally nonprecipitable (soluble) fractions, are obtained via the free-radical copolymerization of N-vinylcaprolactam and the specified comonomers that is initiated by a persulfate–tertiary amine redox system in a medium of 10% aqueous dimethyl sulfoxide (DMSO) at 65°C. It is shown that the soluble fractions of the synthesized copolymers exhibit catalytic activity in the reaction of hydrolysis of 4-nitrophenyl propionate (NPP) at a temperature above the coil-to-globule transition. |
| Databáze: | OpenAIRE |
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