Solvent extraction behavior of trivalent metal ions in diglycolamides having same carbon to oxygen ratio
| Autor: | M. P. Antony, Jammu Ravi, P. R. Vasudeva Rao, T. G. Srinivasan, K. A. Venkatesan |
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| Rok vydání: | 2015 |
| Předmět: |
Process Chemistry and Technology
General Chemical Engineering Metal ions in aqueous solution Extraction (chemistry) chemistry.chemical_element Filtration and Separation Nanotechnology General Chemistry 010402 general chemistry 010403 inorganic & nuclear chemistry 01 natural sciences Diluent Oxygen 0104 chemical sciences chemistry.chemical_compound chemistry Third phase Nitric acid Solvent extraction Carbon Nuclear chemistry |
| Zdroj: | Separation Science and Technology. 51:32-40 |
| ISSN: | 1520-5754 0149-6395 |
| DOI: | 10.1080/01496395.2015.1085874 |
| Popis: | Various diglycolamides (DGAs), N,N,N’,N’-tetraoctyl diglycolamide (TODGA), N,N-di-2-ethylhexyl-N’,N’-di-octyl diglycolamide (DEHDODGA), N,N,N’,N’-tetra-2-ethylhexyl diglycolamide (TEHDGA), N,N-di-decyl-N’,N’-di-hexyl diglycolamide (D2DHDGA), N,N-di-butyl-N’,N’-di-dodecyl diglycolamide (DBD3DGA), N,N,N’,N’-tetra-hexyl diglycolamide (THDGA), and N,N,N’,N’-tetradecyl diglycolamide (TDDGA) have been synthesized and studied for the extraction of Am(III) and Eu(III) from nitric acid medium. An attempt was made to understand the extraction and third phase formation behavior of trivalent metal ions in these DGAs. Our results revealed that despite having the same carbon to oxygen ratio in these DGAs, the third phase formation behavior and extractions achieved in these DGAs are significantly different. |
| Databáze: | OpenAIRE |
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