Testing New Ruthenium Complexes bearing Chiral 1,2,4-Triazol-5-ylidene ­Ligands as Catalysts for Asymmetric Olefin Metathesis

Autor:	Michał Pieczykolan, Karol Grela, Krzysztof Woźniak, Maura Malinska, Rafał Gawin
Rok vydání:	2013
Předmět:	Olefin metathesis Chemistry Stereochemistry Organic Chemistry Enantioselective synthesis Salt metathesis reaction chemistry.chemical_element Ring-opening metathesis polymerisation Metathesis Combinatorial chemistry Acyclic diene metathesis Catalysis Ruthenium
Zdroj:	Synlett. 24:1250-1254
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-0033-1338877
Popis:	New ruthenium complexes bearing chiral 1,2,4-triazol-5-ylidene ligands were obtained and tested in model asymmetric metathesis reactions. Low enantioselectivity in asymmetric ring-closing metathesis (ARCM) and moderate enantioselectivity in asymmetric ring-opening/ring-closing metathesis (AROCM) was observed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::100115226e2a778254c647dfafcc3eb8 https://doi.org/10.1055/s-0033-1338877 Zobrazit plný text záznamu