DSC study of stabilizing effect of antioxidant mixtures in styrene-butadiene rubber
Autor: | Peter Šimon, Karol Kosár, Jan Uhlar, Zuzana Cibulková, Andrea Černá, Peter Lehocký |
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Rok vydání: | 2011 |
Předmět: |
Antioxidant
Materials science Styrene-butadiene genetic structures medicine.medical_treatment Condensed Matter Physics chemistry.chemical_compound Differential scanning calorimetry chemistry Natural rubber visual_art medicine visual_art.visual_art_medium Organic chemistry Physical and Theoretical Chemistry |
Zdroj: | Journal of Thermal Analysis and Calorimetry. 108:415-419 |
ISSN: | 1572-8943 1388-6150 |
DOI: | 10.1007/s10973-011-1963-1 |
Popis: | The type of cooperation between antioxidants in the binary mixtures of four substituted diphenylamines and phenotiazine in the stabilization of styrene-butadiene rubber has been tested. Thermooxidation of the samples has been studied by differential scanning calorimetry under non-isothermal conditions. The protection factors of the individual stabilizers and their mixtures were determined. The synergy factors were applied to asses the type of cooperation of antioxidants in the mixtures. From their values it can be concluded that the type of cooperation depends on temperature. The highest synergistic effect has been observed for the mixture of phenotiazine and [4-(1-methyl-1-phenyl-ethyl)-phenyl]-phenylamine. |
Databáze: | OpenAIRE |
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