Photoacoustic detection of NO2 and N2O using quantum cascade lasers

Autor: Helion Vargas, M. Angelmahr, Peter Hess, András Miklós, J. A. P. Lima
Rok vydání: 2006
Předmět:
Zdroj: Applied Physics B. 85:279-284
ISSN: 1432-0649
0946-2171
DOI: 10.1007/s00340-006-2357-0
Popis: Pulsed quantum cascade lasers (QCLs) with 6.2-μm and 8-μm wavelengths and a differential photoacoustic (PA) detector were used to measure concentrations of NO2 and N2O in the sub-ppmv range at ambient pressure. The QCL temperatures were tuned between -40 °C and 30 °C. Good agreement was found between measured PA vibrational spectra and simulated HITRAN spectra of both nitrogen oxides. The PA signals showed a linear dependence on the concentration in the investigated 0.5–50 ppmv region in both cases. The results for N2O are compared with a PA measurement of N2O at 2.9 μm using a grazing-incidence optical parametric oscillator.
Databáze: OpenAIRE