Exalted Resonance Demands in the Substituent Effects on the Acetolyses of 2-Arylethyl Trifluoromethanesulfonates Destabilized by CN and CF3Groups

Autor:	Shoko Tsuboya, Ken Hazama, Satoshi Usui, Yukihiro Umezawa, Mutsuo Okamura
Rok vydání:	2009
Předmět:	chemistry.chemical_compound Trifluoromethyl chemistry Substituent Organic chemistry General Chemistry Resonance (chemistry) Medicinal chemistry
Zdroj:	Bulletin of the Chemical Society of Japan. 82:254-260
ISSN:	1348-0634 0009-2673
DOI:	10.1246/bcsj.82.254
Popis:	Substituent effects on the acetolysis rates of 2-aryl-1-cyano-1-(trifluoromethyl)ethyl trifluoromethanesulfonates (α-OTf) and 2-aryl-2-cyano-2-(trifluoromethyl)ethyl trifluoromethanesulfonates (β-O...
Databáze:	OpenAIRE
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