Synthesis of 1,9-Disubstituted Phenalenes and their Structural Assignment by HMQC and HMBC Experiments

Autor:	B. Meltzheim, L. Germanaud, Robert Faure, F. Tort, Bernard Waegell
Rok vydání:	1996
Předmět:	Nucleophile Heteronuclear molecule Computational chemistry Chemistry Organic chemistry General Materials Science General Chemistry Phenalenes
Zdroj:	Magnetic Resonance in Chemistry. 34:383-388
ISSN:	1097-458X 0749-1581
DOI:	10.1002/(sici)1097-458x(199605)34:5<383::aid-omr881>3.0.co;2-b
Popis:	The reaction of phenalenone with various sulphur-derived nucleophiles gave 1-hydroxy-9-alkyl- or -aryl-thiophenalenes. The complexity of the aromatic 1H and 13C signals does not allow straightforward assignments. These were rendered possible by the use of two-dimensional 1H-detected heteronuclear one-bond (HMQC) and multiple-bond (HMBC) correlation techniques.
Databáze:	OpenAIRE
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