Coaxial electrospun polyurethane core-shell nanofibers for shape memory and antibacterial nanomaterials
| Autor: | Jinlian Hu, H. T. Zhuo, S. J. Chen |
|---|---|
| Rok vydání: | 2011 |
| Předmět: |
Nanostructure
Materials science Polymers and Plastics Scanning electron microscope General Chemical Engineering Organic Chemistry Smart polymer Electrospinning Nanomaterials chemistry.chemical_compound chemistry Nanofiber Polycaprolactone Materials Chemistry Physical and Theoretical Chemistry Composite material Polyurethane |
| Zdroj: | Express Polymer Letters. 5:182-187 |
| ISSN: | 1788-618X |
| DOI: | 10.3144/expresspolymlett.2011.16 |
| Popis: | A novel kind of shape memory polyurethane (SMPU) nanofibers with core-shell nanostructure is fabricated using coaxial electrospinning. Transmission electron microscopy (TEM) and scanning electron microscopy (SEM) results show that nanofibers with core-shell structure or bead-on-string structure can be electrospun successfully from the core solution of polycaprolactone based SMPU (CLSMPU) and shell solution of pyridine containing polyurethane (PySMPU). In addition to the excellent shape memory effect with good shape fixity, excellent antibacterial activity against both gram- negative bacteria and gram-positive bacteria are achieved in the CLSMPU-PySMPU core-shell nanofiber. Finally, it is pro- posed that the antibacterial mechanism should be resulted from the PySMPU shell materials containing amido group in ! position and the high surface area per unit mass of nanofibers. Thus, the CLSMPU-PySMPU core shell nanofibers can be used as both shape memory nanomaterials and antibacterial nanomaterials. |
| Databáze: | OpenAIRE |
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