Simplification and extension of a predictive group contribution method for estimating heavy organic pure compound vapor pressures I. Hydrocarbons
| Autor: | Laurent Trassy, Evelyne Neau, Laurent Avaullee, Lucie Coniglio, Christelle Crampon |
|---|---|
| Rok vydání: | 2004 |
| Předmět: |
chemistry.chemical_classification
Work (thermodynamics) Equation of state Component (thermodynamics) Vapor pressure Chemistry General Chemical Engineering General Physics and Astronomy Thermodynamics Group contribution method Hydrocarbon Group (periodic table) Physics::Chemical Physics Physical and Theoretical Chemistry Shape factor |
| Zdroj: | Fluid Phase Equilibria. 216:95-109 |
| ISSN: | 0378-3812 |
| DOI: | 10.1016/j.fluid.2003.10.003 |
| Popis: | In this work, a revision of a predictive model previously proposed by Coniglio for the calculation of pure component vapor pressures by means of the Peng–Robinson equation of state is presented. A new expression for the shape factor m, more suitable for heavy components, has been suggested by Trassy and a simplification of the group contributions is proposed. In this part I, the method is applied to alkanes, naphthenes, aromatic hydrocarbons, alkenes and alkynes. Results obtained on vapor pressures are compared, when possible, to those obtained using the previous versions. A prediction for heavier hydrocarbons is also presented. This new version offers a good compromise between good results and simplicity. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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