Perfluoroalkylation through Cross-Metathesis between Alkenes and (Perfluoroalkyl)propenes

Autor:	Martin Kotora, Barbara Eignerová, Martin Dračínský
Rok vydání:	2008
Předmět:	Reaction conditions Chemistry Organic Chemistry Organic chemistry Physical and Theoretical Chemistry Metathesis Selectivity Catalysis
Zdroj:	European Journal of Organic Chemistry. 2008:4493-4499
ISSN:	1099-0690 1434-193X
DOI:	10.1002/ejoc.200800230
Popis:	A new approach to perfluoroalkylated compounds based on cross-metathesis between perfluoropropenes and terminal alkenes has been developed. The reaction is catalysed with high efficiency and selectivity by the Hoveyda–Grubbs second-generation catalyst under mild reaction conditions. The method is applicable to a wide range of compounds, such as vinylaromatics, isoprenoids and saccharides.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
Databáze:	OpenAIRE
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