Direct-Deposition Infrared Spectrometry with Gas and Supercritical Fluid Chromatography

Autor: Elizabeth. Shafter, Steven M. Pyle, Donald F. Gurka, Richard Titus
Rok vydání: 1994
Předmět:
Zdroj: Analytical Chemistry. 66:2521-2528
ISSN: 1520-6882
0003-2700
DOI: 10.1021/ac00087a017
Popis: A direct-deposition Fourier transform infrared (FT-IR) system has been evaluated for applicability to gas chromatography (GC) and supercritical fluid chromatography (SFC) of environmental analytes. A 100-μm i.d. fused-silica transfer line was used for GC, and a 50-μm transfer line with an integral restrictor was used for SFC. Minimum identifiable quantities for GC/FT-IR ranged from 0.5 to 2.0 ng. This is over an order of magnitude better than those reported for light-pipe FT-IR by this laboratory
Databáze: OpenAIRE