Iron(II)-.alpha.-Amino Acid Complexes from Nonprotic Solutions: Reactions of [Fe(Mes)2(phen)] with .alpha.-Amino Acids and the Structures of Bis(L-Prolinato)(1,10-phenanthroline)iron(II) and Bis(D-prolinato)(1,10-phenanthroline)iron(II)

Autor:	Carlo Floriani, Angiola Chiesi-Villa, Corrado Rizzoli, C. Philippe Magill
Rok vydání:	1994
Předmět:	chemistry.chemical_classification Stereochemistry Phenanthroline Aryl Crystal structure Medicinal chemistry Amino acid Inorganic Chemistry chemistry.chemical_compound Monomer chemistry X-ray crystallography Molecule Proline Physical and Theoretical Chemistry
Zdroj:	Inorganic Chemistry. 33:1928-1933
ISSN:	1520-510X 0020-1669
Popis:	The arylation of FeCl 2 (THF) 1.5 in THF with MesMgBr (Mes=1,3,5-Me 3 C 6 H 2 ) in the presence of 9,10-phenanthroline (phen) led to the crystalline [Fe(phen)(Mes) 2 ], 1, which contains a tetrahedral iron(II) σ-bonded to two aryl groups. They can be removed by a variety of protic ligands under aprotic conditions. The reaction of 1 with amino acids AH led to the isolation of monomeric iron(II)-amino acid complexes [Fe(phen)(A) 2 ]
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0ef51ac3df44c3ba9404ff388ffc7f2a https://doi.org/10.1021/ic00087a032 Zobrazit plný text záznamu