Face-to-face stacking of caffeinium and [PMVI12O40]3− ions: A synthon for crystal engineering with purine bases
| Autor: | A. V. Shtemenko, Olha S. Panteleieva, Kostiantyn V. Domasevitch |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Materials science
010405 organic chemistry Synthon Supramolecular chemistry Stacking Ionic bonding 010402 general chemistry Crystal engineering 01 natural sciences 0104 chemical sciences Ion Inorganic Chemistry Crystallography Materials Chemistry Physical and Theoretical Chemistry Topology (chemistry) |
| Zdroj: | Inorganic Chemistry Communications. 94:119-122 |
| ISSN: | 1387-7003 |
| DOI: | 10.1016/j.inoche.2018.06.014 |
| Popis: | Ionic polyoxometales (Hcaf)3[PM12O40]·6H2O [M = Mo, W; caf = caffeine] exhibit unusual supramolecular structure dominated by multiple anion-π interactions, which occur at both axial sides of the caffeinium cations. These cations, when stacked to every of six square faces of POM cuboctahedra, afford supramolecular boxes and the resulting non-covalent cubic framework (α-Po topology) is generated by face-sharing of the boxes. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect