Nonisothermal crystallization and morphology of poly(butylene succinate)/layered double hydroxide nanocomposites

Autor: Yu-mei Shi, Wanxi Zhang, Zhiyong Wei, Guangyi Chen, Mei-qiu Zhan
Rok vydání: 2012
Předmět:
Zdroj: Chinese Journal of Polymer Science. 31:187-200
ISSN: 1439-6203
0256-7679
DOI: 10.1007/s10118-013-1200-4
Popis: Biodegradable poly(butylene succinate) (PBS) and layered double hydroxide (LDH) nanocomposites were prepared via melt blending in a twin-screw extruder. The morphology and dispersion of LDH nanoparticles within PBS matrix were characterized by transmission electron microscopy (TEM), which showed that LDH nanoparticles were found to be well distributed at the nanometer level. The nonisothermal crystallization behavior of nanocomposites was extensively studied using differential scanning calorimetry (DSC) technique at various cooling rates. The crystallization rate of PBS was accelerated by the addition of LDH due to its heterogeneous nucleation effect; however, the crystallization mechanism and crystal structure of PBS remained almost unchanged. In kinetics analysis of nonisothermal crystallization, the Ozawa approach failed to describe the crystallization behavior of PBS/LDH nanocomposites, whereas both the modified Avrami model and the Mo method well represented the crystallization behavior of nanocomposites. The effective activation energy was estimated as a function of the relative degree of crystallinity using the isoconversional analysis. The subsequent melting behavior of PBS and PBS/LDH nanocomposites was observed to be dependent on the cooling rate. The POM showed that the small and less perfect crystals were formed in nanocomposites.
Databáze: OpenAIRE
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