Investigation of vacancy formation and phase transformations in uranium by positron annihilation

Autor: H. Matter, W. Triftshäuser, J. Winter
Rok vydání: 1980
Předmět:
Zdroj: Journal of Nuclear Materials. 88:273-278
ISSN: 0022-3115
DOI: 10.1016/0022-3115(80)90283-4
Popis: Measurements of the positron annihilation coincidence count rate at the peak of the angular correlation curve (CCR) in uranium were performed as a function of temperature between 550 and 1350 K. The α → β and β → γ phase transformations are reflected by discontinuities of the CCR. The low temperature slope of the curve, the change at the α → β transition at 941 K, and the initial slope in the β phase can be very well described by linear thermal expansion. The jump of the CCR at 1048 K is predominantly due to the vacancy trapping effect. Applying the trapping model to the data in the 7 phase, a lower limit of about 1 eV has been obtained for the monovacancy formation energy EF1v. This result leaves only a very small value for the vacancy migration energy EM1v.
Databáze: OpenAIRE