The preparation and pyrolysis of some (polyfluoro-1,3-cycloheptadiene)iron tricarbonyl complexes

Autor:	J.C. Tatlow, P. Dodman
Rok vydání:	1974
Předmět:	Inorganic Chemistry chemistry.chemical_compound Chemistry Scientific method Organic Chemistry Materials Chemistry Organic chemistry Triiron dodecacarbonyl Physical and Theoretical Chemistry Spectral data Biochemistry Pyrolysis
Zdroj:	Journal of Organometallic Chemistry. 67:87-92
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)93688-x
Popis:	Some new (polyfluoro-1,3-cycloheptadiene)iron tricarbonyl complexes have been prepared by the reaction of triiron dodecacarbonyl with decafluoro-1,3-cycloheptadiene, 1H-nonafluoro-1,3-cycloheptadiene and 1H,4H-octafluoro-1,3-cycloheptadiene. Spectral data for the complexes are described. Pyrolysis of the complexes at 440° was found to give polyfluorobenzenes and a possible mechanism for this process is proposed.
Databáze:	OpenAIRE
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