ChemInform Abstract: The Ethyne-Ethylidene Rearrangement: Formation of 3-Ethynyl- and 1- Ethynylacenaphthylene on Flash Vacuum Pyrolysis of 1,7- Diethynylnaphthalene

Autor:	Frank W. Eastwood, Roger F. C. Brown, Neil Wong
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Flash vacuum pyrolysis Chemistry Closure (topology) General Medicine Cleavage (embryo) Ring (chemistry) Photochemistry Acenaphthylene
Zdroj:	ChemInform. 24
ISSN:	0931-7597
DOI:	10.1002/chin.199327168
Popis:	1,7-Diethynylnaphthalene on flash vacuum pyrolysis at 1100°C/0.05 mm gave 3-ethynylacenaphthylene and 1-ethynylacenaphthylene (80:20). This finding is interpreted in terms of initial formation of 3-ethynylacepnaphthylene, ring closure of some of this compound to the hypothetical cyclopent[ bc ]acenaphthylene and cleavage to give 1-ethynyl- and 3-ethynylacenaphthylene.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0e8ca1a120a5ede2f3fb1791ae7af1e5 https://doi.org/10.1002/chin.199327168 Zobrazit plný text záznamu Plný text