Neue Synthese von Aceton-d6

Autor: H. Hunziker, Hs.H. Günthard, R. Meyer, W. E. Good
Rok vydání: 1962
Předmět:
Zdroj: Helvetica Chimica Acta. 45:59-62
ISSN: 0018-019X
Popis: Pure acetone-d6 has been prepared by reaction of heavy water with propyne-d4 in the liquid phase and a mercury catalyst. Propyne-d4 was obtained by hydrolysis of magnesium carbide Mg2C3 with heavy water. A practical procedure for 20 g amounts of acetone-d6 is given in detail. Its over-all consumption of heavy water exceeds the theoretical amount by only 5–10%.
Databáze: OpenAIRE