Hydrothermal synthesis, crystal structure and magnetic property of oxalate-bridged iron 1D chain coordination polymer

Autor:	Feng-Xia Ma, Kun Liu, Hai-Jun Pang, Fan-Xia Meng, Ya-Guang Chen, Dong-Mei Shi
Rok vydání:	2007
Předmět:	Coordination polymer Metals and Alloys Infrared spectroscopy Crystal structure Magnetic susceptibility Oxalate Inorganic Chemistry Crystallography chemistry.chemical_compound chemistry Materials Chemistry Hydrothermal synthesis Organometallic chemistry Monoclinic crystal system
Zdroj:	Transition Metal Chemistry. 32:981-984
ISSN:	1572-901X 0340-4285
Popis:	A novel oxalate-bridged iron coordination polymer, Fe2(phen)2(C2O4)2(1) has been hydrothermally synthesized and characterized by elemental analyses, IR spectrum, TGA-DTA analysis, and single-crystal X-ray diffraction. Compound (1) crystallizes in the monoclinic system, space group P2(1), the final R is 0.0486. The tetradentate-chelating coordination mode of oxalate anion creates an infinite 1D iron (II) oxalate chain structure and from which a 2D network is constructed by π–π interactions of phen rings. The temperature-dependent magnetic susceptibility measurement indicates the existence of a weak antiferromagnetic coupling between FeII ions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0e78210a48434d4659870f34159c8526 https://doi.org/10.1007/s11243-007-0264-9 Zobrazit plný text záznamu Full text from SpringerLink