Retardation of monomolecular reactions in the solid phase

Autor:	G. M. Nazin, G. B. Manelis, Yu. M. Burov
Rok vydání:	1999
Předmět:	Crystal Reaction rate constant Retardation effect Chemistry Phase (matter) Thermal decomposition Solid-state Physical chemistry General Chemistry Crystal structure Decomposition
Zdroj:	Russian Chemical Bulletin. 48:1250-1254
ISSN:	1573-9171 1066-5285
DOI:	10.1007/bf02495284
Popis:	The rate constants of initial monomolecular stages of thermal decomposition in the solid phase were measured for 22 organic compounds. The ratio of rate constants of decomposition in the melt and solid state, characterizing the reaction retardation in the crystal lattice, was determined. The retardation effect was compared to the physical properties of the crystal.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0e7619fda474ffefcee11db6d003d858 https://doi.org/10.1007/bf02495284 Zobrazit plný text záznamu Full text from SpringerLink